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Thursday, November 5, 2020 | History

2 edition of The Chemistry of ketenes, allenes, and related compounds found in the catalog.

The Chemistry of ketenes, allenes, and related compounds

The Chemistry of ketenes, allenes, and related compounds

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  • 11 Currently reading

Published by J. Wiley in Chichester, New York .
Written in English

    Subjects:
  • Ketenes.,
  • Allenes.

  • Edition Notes

    Includes bibliographies and index.

    Statementedited by Saul Patai.
    SeriesChemistry of functional groups
    ContributionsPatai, Saul.
    Classifications
    LC ClassificationsQD305.K2 C46
    The Physical Object
    Pagination2 v. (xiv, 982 p.) :
    Number of Pages982
    ID Numbers
    Open LibraryOL4426169M
    ISBN 100471276715
    LC Control Number79042899

    Overall, the book is well-written and provides plenty of food for thought for specialists in palladium(II) chemistry, as many aspects of palladium-activated allene reactivity are explored, but not totally solved, in the course of this work. Being a thesis, the book also benefits from a comprehensive experimental section at the end of each chapter.   allene (plural allenes) (organic chemistry) Any of a class of hydrocarbons having two double bonds from one carbon atom to two others - R 2 C=C=CR 2; especially the parent compound CH 2 =C=CH 2. (organic chemistry) Any derivative of such hydrocarbons. Translations.


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The Chemistry of ketenes, allenes, and related compounds Download PDF EPUB FB2

The most complete resource in functional group chemistry. Patai's Chemistry of Functional Groups is one of chemistry's landmark book series in organic chemistry.

An indispensible resource for the organic chemist, this is the most comprehensive reference available in functional group chemistry. Founded in by the late Professor Saul Patai, the aim of Patai's Chemistry of Functional Groups is to cover.

Buy The Chemistry of Ketenes Allenes and Related Compounds, Part 1 (Patai's Chemistry of Functional Groups) (Pt. 1) on FREE SHIPPING on qualified orders. The most complete resource in functional group chemistry Patai's Chemistry of Functional Groups is one of chemistry's landmark book series in organic chemistry.

An indispensible resource for the organic chemist, this is the most comprehensive reference available in functional group : Saul Patai. Try the new Google Books. Check out the new look and enjoy easier access to your favorite features. Try it now. No thanks.

Try the new Google Books Get print book. No eBook available The Chemistry of ketenes, allenes, and related compounds, Volume 1. Saul Patai. Wiley, - Science - pages. 0 Reviews. Download Citation | The Chemistry of Ketenes Allenes and Related Compounds, Part 2 | The most complete resource in functional group chemistry Patai's Chemistry of Functional Groups is one of.

The molecular structure of allenes and ketenes VI [1] circular dichroism spectroscopy as a tool for the detection and assignment of electronic transitions in phenylallenecarboxylic acids. Berichte der Bunsengesellschaft für physikalische Chemie79 (7), DOI: /bbpcCited by: Buy Chemistry of Ketenes, Allenes and Related Compounds: Pt.

2 (Patai′s Chemistry of Functional Groups) by Saul Patai (ISBN: ) from Amazon's Book Store. Everyday low prices and free delivery on eligible : Saul Patai.

Palladium-Catalyzed Synthesis of Endocyclic Allenes and Their Application in Stereoselective [2 + 2]Cycloaddition with Ketenes. Organic Letters11 allenes, DOI: /olc. Meng Tang, Chun-An Fan, Fu-Min Zhang, Yong-Qiang Tu, Wen-Xue Zhang and Ai-Xia by: Introduction The recent discovery of several potent antiturnor antibiotics containing (Z)-enediynes or rented systems has pushed the exploration of enediynes to the forefront of chemical and biological research.1 In addition to their biological activity, which results in the cleavage of DNA, these compounds are also of interest because of their unique structural by: Brady, W.

In The Chemistry of Ketenes, Allenes, and Related Compounds; Patai, S. Ed.; Wiley: New York,part 1, ch. O Cl Cl O O R CO 2 H R Cl Cl Cl O OH N N O O Cl Cl CO 2 Bn CO 2 Bn H H O O HO Ph 3 SnH or Zn AcONHEt 3 acetone/H 2 O Base 1. File Size: KB. Request PDF | Ketenes, Ketene Dimers, and Related Substances | The parent ketene [] and its dimer diketene [] are of significant industrial importance, serving as starting material.

The chemistry of ketenes, allenes and related compounds (2 parts) Allenes chemistry of the sulphonium group (2 parts) Supplement A: The chemistry of double-bonded functional groups (3 volumes, 6 parts). Theoretical methods and their application to ketenes and allenes / Clifford E.

Dykstra and Henry F. Schaefer --Structural chemistry / Wolfgang Runge --Chirality and chiroptical properties / Wolfgang Runge --The thermodynamics of allenes, ketenes and related compounds / Richard L. Deming and Claus A. Wulff --Detection, determination and.

Description. This two-volume handbook covers all the important aspects and facts related to this hot topic. With their excellent contributions an international team of outstanding authors highlight the multifarious uses and classes of allenes, making this an indispensable book for every organic chemist.

Get this from a library. The chemistry of ketenes, allenes and related compounds / 1. The Preparation of Allenes and Cumulenes, In The Chemistry of Ketenes, Allenes and Related Compounds, Part 1 Patai S.

John Wiley & Sons; New York: p 2 Cited by: A Brief History of Allenes Jacobus H. van't Hoff predicts the correct structures of alenes and cumulenes as well as their axial chirality (La Chemie dans l'Espace, Bazendijk: Rotterdam, ) First axially chiral allene synthesized by P.

Maitland and W. Mills (Nature, ; J. Chem. Soc.). In an attempt to prove the nonexistence of these. 1,2,3,4-tetrahydroisoquinoline (THIQ) mediates a practical synthesis of 1,3-disubstituted allenes from terminal alkynes and aldehydes under mild conditions in the presence of CuBr first and then ZnI 2.

A wide range of aldehydes and terminal alkynes are tolerated, affording the allene products in good yield. Hai Dao 25/01/ Baran Group Meeting Ketenes A brief history Synthesis of urea = the starting point of modern organic chemistry.

Wedekind's proposal for the formation of ketene equivalent (confirmed by Staudinger ) Wolff rearrangement, Wolff, L. Liebigs Ann. Chem., Wolff adopt a ketene structure in First synthesis and characterization of a File Size: KB.

3d The Chemistry of Ketenes, Allenes and Related Compounds Parts 1 and 2: Patai S. Wiley; Chichester: 4 Lü L. Ph.D. Dissertation Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences; P.

of China: Cited by: 2. The chemistry of ketenes, allenes and related compounds, John Wiley and Sons Ltd, London () See for a comprehensive review on allene chemistry:S. Patai(Editor) 2Cited by: Patai Chemistry of Ketenes Allenes and Related Compounds (PATAI'S Chemistry of Functional Groups) (Pt.

2) by Saul Patai and a great selection of related books, art and collectibles available now at Synthesis of Allenes by 1,2-Elimination Author(s): Roly J.

Armstrong*. Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Oxford, OX1 3TA, United KingdomCited by: 1.

Review on the prepn of stable ketenes: R. Ward in The Chemistry of Ketenes, Allenes and Related Compounds Part 1, S. Patai, Ed. (Wiley, New York, ) pp ; All operations with ketene should be carried out in an efficient hood (Andreades, Carlson). Melting point. Functionalized allenes, such as allenyl isothiocyanates, isoelenocyanates, isocyanates, thiocyanates, azides, azo compounds and others, are easily available by these methods.

In several cases, however, the title compounds show high reactivity, which leads to rapid intermolecular or intramolecular successive by: 1. Allenes are organic compounds in which one carbon atom has double bonds with each of its two adjacent carbon centres.

Allenes are classified as cumulated parent compound of this class is propadiene, which is itself also called nds with an allene-type structure but with more than three carbon atoms are members of a larger class of compounds called cumulenes with X=C=Y. He photoelectron (p.e.) spectra for the donor-substituted allenes RCH [[double bond, length as m-dash]] C [[double bond, length as m-dash]] CH[R =(CH)C (), N(CH Cited by: 9.

The Chemistry of Organic Silicon Compounds Saul Patai, Zvi Rappoport Organosilicon compounds are key organometallic compounds (R-Si) which have many uses in materials science and in metallurgy.

A ketene is an organic compound of the form R′R″C=C=O, where R and R' are two arbitrary monovalent chemical groups (or two separate substitution sites in the same molecule). The name may also refers to the specific compound ethenone H 2 C=C=O, the simplest ketene.

Although they are highly useful, most ketenes are used as reagents in a chemical procedure, they are typically.

Ozonation in Organic Chemistry, Volume II: Nonolefinic Compounds discusses the reactions of ozone with organic compounds.

The book presents the role of ozone in air pollution. It demonstrates the use of ozonation in wastewater purification, effects of ozone on biological systems, and degradation of Edition: 1.

Abstract The main scope of the research presented in this thesis is the investigation of the viabilit y of polymer- bound ketenes and allenes, and of their reactions.

These studies represent a continuation both of the current developments in polyrner-bound : Adel Rafai Far. B Chemistry of Allenes. The properties of allenes are similar to those of alkenes, although the pure compounds often are difficult to prepare and are not indefinitely stable.

Allenes undergo many of the usual double-bond reactions, being readily hydrogenated, adding bromine, and being oxidized with potassium permanganate solution. New routes to enantiopure allenes are important because of their documented utility in organic synthesis.

1 – 3 We recently reported an efficient kinetic resolution of 1,3-disubstituted allenes using enantiopure ethylenebis (tetrahydroindenyl) (ebthi) imidozirconium compounds. 4 In the course of that investigation, a remarkable selective inversion of allene configuration was observed (Figure 1).Cited by: We report a stereoselective regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes with pinacolborane (HBpin) in the presence of cobalt catalysts generated from bench-stable Co(acac) 2 and bisphosphine ligands.

An interesting correlation between the regioselectivity of this hydroboration and the bite angles of bisphosphine ligands was identified. A novel rhodium-catalyzed linear codimerization of alkyl phenyl ketenes with internal alkynes to dienones and a novel synthesis of furans by an unusual cycloaddition of diaryl ketenes with internal alkynes have been developed.

These reactions proceed smoothly with the same rhodium catalyst, RhCl(PPh 3) 3, and are highly dependent on the structure and reactivity of the starting by: 9.

The generation of neutral and ionized allenes, cumulenes and hetero-cumulenes by electron impact. Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their “click-like” nature.

The chapters are structured according to the number of carbon atoms in the system, including coverage of: introduction to the chemistry. In aldehydes and ketones, which together are referred to as carbonyl compounds, C=O double bonds are part of a carbonyl group, C sp2 =O.

Carboxylic acids, carboxylic esters, and carboxylic amides, as well as all carboxylic acid derivatives used as acylating agents (see Section ) are termed collectively as carboxyl compounds and are thereby distinguished from the carbonyl compounds.

These are more facile synthetic route than those previously reported. These findings would contribute to the development of efficient synthetic methods for biologically active compounds containing a complex structure. Total Synthesis of Bioactive Natural Products by Palladium-Catalyzed Domino Cyclization of Allenes and Related Compounds - eBook.

View Notes - ketene from CHEM at Indian Institute of Technology, Kharagpur. [2+2] Cycloadditions of Ketenes An Evans Group Afternoon Seminar Jake Janey October 8, Leading. SYNTHESIS AND CHEMISTRY OF (TRIALKYLSILYL)VINYLKETENES by Dawn M.

Bennett Submitted to the Department of Chemistry on in partial fulfillment of the requirements for the Degree of Doctor of Philosophy ABSTRACT The properties of silylketenes differ dramatically from those of ketenes.Total synthesis of the bioactive natural products, pachastrissamine, lysergic acid, lysergol and isolysergol, by palladium-catalyzed domino cyclization of allenes and related compounds is investigated ; Gives an insight to the development of efficient synthetic approaches for biologically active compoundsBrand: Springer Japan.catalog books, media & more in the Stanford Libraries' collections articles+ journal articles & other e-resources Search in All fields Title Author/Contributor Subject Call number Series search for Search.